The following image shows a river's watershed.
A group of farms need water for irrigation and want to set up machinery that would pump water from the river. The farmers consider pumping water from the four locations indicated in the image. Which location would have the smallest impact on the watershed?

An enzymatic hydrolysis of fructose-1-p, fructose-1-p(aq) + h2o(l) - fructose (aq) + pi (aq) was allowed to proceed to equilibrium at 25°c. the original concentration of fructose-1-p was 0.2 m, but when the system had reached equilibrium, the concentration of fructose-1-p was only 6.52 x 10^-5 m. calculate the equilibrium constant for this reaction and the free energy of hydrolysis of fructose-1-p.