Chemistry, 19.07.2019 12:30 ErrorNameTaken505

How does increasing concentration/ temperature/ surface area affect the yield of products in a chemical reaction (not reversible)

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Increasing concentration, temperature and surface area will increase the yield of products.

Explanation:
Concentration:
Increase in concentration of reactants will increase the number of reactants per unit volume. Therefore, the probability of collisions will increase hence, it will result in the increase in yield.

Temperature:
Increase in temperature increases the kinetic energy of reactants. Therefore, the increase in velocity of reactants results in the collisions with high energy. It makes it feasible for reactants to attain the optimum energy (activation energy) to convert into products with good yield.

Surface Area:
The reactants in grinded / powder form reacts fast as compared to solid form. In fact, grinding results in increase of the surface area of reactants. Greater surface area increases the probability of reactants to colloid. Hence, increases the yield.

Answer from: Quest

answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 : $4x (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) h rxn = -600 kj/mol$

equation 2 : $2x (s) + 3cl_{2} (g) \rightarrow 2xcl_{3} (s) h rxn = -800 kj/mol$

equation 3 : $4xcl_{3} (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) + 6cl_(2} h rxn = -200 kj/mol$

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 : $4xcl_{3} (s) \rightarrow 4x (s) + 6cl_{2} ( h rxn = (+800) \times 2 kj/mol$

let us add equation 1 & 4

$4x (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) h rxn = -600 kj/mol$

$4xcl_{3} (s) \rightarrow 4x (s) + 6cl_{2} ( h rxn = (+1600) kj/mol$

$4xcl_{3} )s) + 3o_{2} \rightarrow 2x_{2}o_{3} (s) + 6cl_{2} (g) h rxn = (+1000) kj/mol$

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

Answer from: Quest

Ithink that the use of creativity in the sciences entails that one produce something out of nothing or from another thing. with this, i think that the he wrote down his results as four parts of the atomic theory is the manifestation of the creativity of john dalton.

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