Why is it incorrect to balance a chemical equation by changing the subscripts?

Explanation for basic character?

Ican determine the molar mass of an element by looking on the under the atomic mass for the element. for example the molar mass of phosphorus is 30.974 grams/mole. avogadro’s number tells me the amount of representative particles in 1 mole of any substance. this means 12.011 gram sample of carbon and a 32.0 gram sample of sulfur have the same number of atoms.

Which of the following describes a compound? (hint: carbon and oxygen bo a. a piece of pure carbon, containing only carbon atoms b. oxygen gas surrounding a solid piece of carbon c. a substance made of two oxygen atoms for each carbon atom carbon and oxygen atoms mixed without being bonded together