Which of these is an empirical formula?

Ibelieve its a because an empirical formula usually has a ch in it your options are a or b

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.