How is my crime scene sketches? what grade are these going to get?

Apeak with a retention time of 407 s has a width at half-height (w1/2) of 7.6 s. a neighboring peak is eluted 17 s later with a w1/2 of 9.4 s. a compound that is known not to be retained was eluted in 2.5 s. the peaks are not baseline resolved. how many theoretical plates would be needed to achieve a resolution of 1.5?

What is the volume of the fluid in the graduated cylinder with accuracy and measured to the correct degree of precision? 41.2 ml 42.0 ml 41.23 ml 41.89 ml

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.