When will le chatelier's principle come into effect? at the beginning of a reaction, when there are only reactants when a reaction has reached chemical equilibrium when a catalyst is added to a reaction mixture when a reaction is occurring but not yet at equilibrium

At a certain temperature the rate of this reaction is first order in hi with a rate constant of : 0.0632s2hig=h2g+i2g suppose a vessel contains hi at a concentration of 1.28m . calculate how long it takes for the concentration of hi to decrease to 17.0% of its initial value. you may assume no other reaction is important. round your answer to 2 significant digits.