Rank these compounds by their expected boiling point. ch3cl, ch4, ch3oh

CH₄ < CH₃Cl < CH₃OH

Explanation:

In all three compounds, the central C atom has four bonds, so the molecules all have a tetrahedral molecular geometry.

The only difference is in one bond:  CH₃-Cl, CH₃-H, and CH₃-OH.

CH₃-Cl: The C-Cl bond is polar, so the strongest intermolecular forces are dipole-dipole.

CH₄: the molecule is symmetrical, so the strongest intermolecular forces are London dispersion forces.

CH₃-OH: The OH group can form hydrogen bonds.

The order of strength of intermolecular forces is

London dispersion forces < dipole-dipole < hydrogen bonds

The order of boiling points is

CH₄ < CH₃Cl < CH₃OH

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