If the temperatures within the two tanks of problem 3.4-9. before opening the valve, had been t = 300 k and 350 k. respectively, what would the final temperature be? b) if the first tank had contained he at an initial temperature of 300 k. and the second had contained a diatomic ideal gas with c 5/2 and an initial tempera- ture of 350 k, what would the final temperature be?

answer: the enthalpy of the overall chemical reaction is +87.88 kj or +88 kj.

according to hess's law, the overall enthalpy of a reaction is the difference between the sum of enthalpy values of all the products and the sum of enthalpy values of all the reactants.

δh(reaction) = ∑nδh(products) - ∑nδh(reactants)

δh(reaction) = [δh +δh] - [δh]

δh(reaction) = [1(-287.02) + 1(0) ] - [1(-374.9)] kj = +87.88 kj

here, δh (pcl3) = -287.02 kj, δh(cl2) = 0, δh(pcl5) = -374.9 kj

therefore, enthalpy of the overall reaction is +87.88 kj or +88 kj.

35. a insulated cylinder of solid gold (k 310 kw/m-k) of radius v2 m and height 5 m is heated at one end until the temperature at each point in the cylinder is given by w(r, y, z) (30 z2)(2-(r2+ y2). determine the rate of heat flow across each horizontal disk given by z 1, z 2, and z 3, identifying which has the greatest rate of heat flow across it.

explanation: