The vibrational wavenumber of br2 323.2/cm. evaluate the vibrational partition function without approximation and plot it's value as a function of temperature. determine the temperature at which the value obtained lies within 5% of the approximate value

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c is having 4 valence electrons and is bonded to three hydrogens and one sulphur atom, therefore, the number of bond pair is equal to four. as all the valence electrons are used in forming the bonds so, there is no lone pair left on carbon.

s is having 6 valence electrons and is bonded to one other sulfur atom and one carbon atom, therefore, the number of bond pair is equal to 2. as only two valence electrons are used in forming the bonds so, four electrons are left. therefore, two lone pairs are present on s.

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