Rainwater collected in akron contains pb, cu and zn at 8.5, 5.0 and 7.5 ug/l. determine these concentrations in units of mol/l (or nmol/l). b) this same rainwater contains 0.8 mg/l ca and 1.2 mg/l mg. determine the hardness of this water in units of mg/l as caco3. hardness is the sum of the concentrations of multivalent cations in the water, which in this case include ca (as ca2+) and mg (as mg2+). hardness is expressed in "equivalent" units or "caco3" units.

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

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