An analytical chemist is titrating 118.3 ml of a 0.3500 m solution of butanoic acid (hc3h7co2) with a 0.400 m solution of koh. the pka of butanoic acid is 4.82. calculate the ph of the acid solution after the chemist has added 115.4 ml of the solution to it. note for advanced students: you may assume the final volume equals the initial volume of koh the solution plus the volume of solution added. round your answer to 2 decimal places.

pH = 12.33

Explanation:

Lets call HA = butanoic acid and A⁻ butanoic acid and its conjugate base butanoate respectively.

The titration reaction is

HA + KOH A⁻ + H₂O + K⁺

number of moles of HA :   118.3 ml/1000ml/L x 0.3500 mol/L = 0.041 mol HA

number of  moles of OH  : 115.4 mL/1000ml/L x 0.400 mol/L  = 0.046 mol A⁻

therefore the weak acid will be completely consumed and what we have is  the unreacted strong base KOH which will drive the pH of the solution since the contribution of the conjugate base is negligible.

n unreacted KOH = 0.046 - 0.041 = 0.005 mol KOH

pOH = - log (KOH)

M KOH = 0.005 mol / (0.118.3 +0.1154)L = 0.0021 M

pOH = - log (0.0021) = 1.66

pH = 14 - 1.96 = 12.33

Note: It is a mistake to ask for the pH of the acid solution since as the above calculation shows we have a basic solution the moment all the acid has been consumed.

some of the qualities most frequently associated with the baroque are grandeur, sensuous richness, drama, vitality, movement, tension, emotional exuberance, and a tendency to blur distinctions between the various arts.

most historians agree that gabriel mouton, the vicar of st. paul’s church in lyons, france, is the “founding father” of the metric system. he proposed a decimal system of measurement in 1670. mouton based it on the length of one minute of arc of a great circle of the earth (now called a nautical mile, 1852 meters). he also proposed the swing-length of a pendulum with a frequency of one beat per second as the unit of length (about 25 cm). a pendulum beating with this length would have been fairly easy to produce, thus facilitating the widespread distribution of uniform standards. over the years, his work was revised, improved, and extended by a number of french scientists.

the political sponsor of weights and measures reform in the french revolutionary national assembly was the bishop of autun, better known as talleyrand. under his auspices, the french academy appointed several committees to carry out the work of developing a usable system of weights and measures for france. one of the committees recommended a decimalized measurement system based upon a length equal to one ten-millionth of the length of a quadrant of the earth’s meridian (i.e., one ten-millionth of the distance between the equator and the north pole).