Is the electrochemical cell spontaneous or not spontaneous as written at 25 ∘c ? spontaneous not spontaneous calculate the potential of the electrochemical cell and determine if it is spontaneous as written at 25 ∘c . pt(s) || sn2+(0.0023 m),sn4+(0.13 m) ‖‖ fe3+(0.11 m),fe2+(0.0037 m) || pt(s) ∘sn4+/sn2+=0.154 ∘fe3+/fe2+=0.771 v

The cell potential is 0.609 V. Given E > 0 the electrochemical cell is spontaneous as written.

Explanation:

Let's consider the oxidation and reduction half-reactions and the global reaction.

Anode (oxidation): Sn²⁺(0.0023 M) ⇒ Sn⁴⁺(0.13 M) + 2 e⁻

Cathode (reduction): 2 Fe³⁺(0.11 M) + 2 e⁻ ⇒ 2 Fe²⁺(0.0037 M)

Global reaction: Sn²⁺(0.0023 M) + 2 Fe³⁺(0.11 M) ⇒ Sn⁴⁺(0.13 M) + 2 Fe²⁺(0.0037 M)

The standard cell potential (E°) is the difference between the standard reduction potential of the cathode and the standard reduction potential of the anode.

E° = E°red,cat - E°red,an

E° = 0.771 V - 0.154 V = 0.617 V

The Nernst equation allows us to calculate the cell potential (E) under the given conditions.

The cell potential is 0.609 V. Given E > 0 the electrochemical cell is spontaneous as written.

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :

there is none because earth is stationary and flat.