Acrylic acid is produced from propylene by the following gas phase reaction: a significant side reaction is the formation of acetic acid: the reactions are carried out at 310°c and 4 bar pressure using a catalyst and air as an oxidant. steam is added in the ratio 8: 1 steam to propylene to stabilize the heat of reaction. if 50% excess air is used (sufficient air so that 50% more oxygen is present than is needed for all the propylene to react by the first reaction), calculate the equilibrium composition of the reactor effluent.

i think it is true since you can test the answer and can use observations to complete it.

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a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.