Select the single best answer. compound a exhibits two singlets in its 1h nmr spectrum at 2.64 and 3.69 ppm and the ratio of the absorbing signals is 2: 3. compound b exhibits two singlets in its 1h nmr spectrum at 2.09 and 4.27 ppm and the ratio of the absorbing signals is 3: 2. which compound corresponds to dimethyl succinate and which compound corresponds to ethylene diacetate? 1455a 1455b dimethyl succinate ethylene diacetate compound a is dimethyl succinate; compound b is ethylene diacetate. compound a is ethylene diacetate; compound b is dimethyl succinate.

Compound A is dimethyl succinate; Compound B is ethylene glycol diacetate.  

Explanation:

The structure of dimethyl succinate (DMS) is (CH₂COOCH₃)₂.

The structure of ethylene glycol diacetate (EGD) is (CH₂OCOCH₃)₂.

The most obvious difference I see is that DMS has an -OCH₃ group, while EGD has a  CH₃CO-  group.

An alkane CH₃ normally appears at 0.9 ppm. The highly electronegative O atom would probably shift the signal downfield to about 3.5 ppm. Add another 0.2 ppm shift for the effect of the C=O group, and the CH₃ group should appear at about 3.7 ppm.

A CH₃CO- group should appear about 1.2 ppm downfield from its normal position at 0.9. That is, it should appear at about 2.1 ppm.

Conclusion:

A is dimethyl succinate; B is ethylene glycol diacetate.  

Confirmatory evidence:

A CH₂ group normally appears at 1.3 ppm. A -CH₂CO-would be shifted down about 1.2 ppm to about 2.5 ppm and a -CH₂O- would be at about 4 ppm.

the answer would be b i believe