In two or more complete sentences describe how a constant volume calorimeter is made, and how it is used to measure energy transfer.

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.

Δu of , in kj/kg, as it isto k, (a)as a of , (b) at , (c) at .