The difference between simple diffusion and facilitated diffusion is that facilitated diffusion

Simple and facilitated diffusion are both similar types of phenomenon where the substances are moved from a region of high concentration to lower concentration across a semi-permeable membrane.

The main difference between them is that the facilitated diffusion requires a special type of protein or carrier molecules in order to transport the substances whereas simple diffusion does not require such molecules. The rate of flow of these substances is high in the facilitated diffusion in comparison to the simple diffusion.

the awnser is group 12

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.