Two gases X and Y are found in the atmosphere in only trace amounts because they decompose quickly. When exposed to ultraviolet light the half-life of X is 1.25h, while that of Y is 150. min. Suppose an atmospheric scientist studying these decompositions fills a transparent 20.0 L flask with X and Y and exposes the flask to UV light. Initially, the partial pressure of X is 25.0% greater than the partial pressure of Y. Will the partial pressure of X ever fall below the partial pressure of Y? (yes or no) If yes, calculate the time it take the partial pressure of X to fall below the partial pressure of Y.

Benzonitrile (c6h5cn) is reduced to two different products depending on the reducing agent used. treatment with lithium aluminum hydride followed by water forms k, which has a molecular ion in its mass spectrum at 107 and the following ir absorptions: 3373, 3290, 3062, 2920, and 1600 cm-1. treatment with a milder reducing agent forms l, which has a molecular ion in its mass spectrum at 106 and the following ir absorptions: 3086, 2850, 2820, 2736, 1703, and 1600 cm-1. l shows fragments in its mass spectrum at m/z = 105 and 77. propose structures for k and l and choose an explanation for how this could be concluded.