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Chemistry, 21.03.2020 00:02 yeayeawhatever3389

Assume that the electronic states of the p electrons of a conjugated molecule can be approximated by the wavefunctions of a particle in a one-dimensional box and that the dipole moment can be related to the displacement along this length by μ = −ex. Show that the transition probability for the transition n = 1 > n = 2 is nonzero, whereas that for n = 1 > n = 3 is zero.

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