When a single alkene monomer, such as ethylene, is polymerized, the product is a homopolymer. If a mixture of two alkene monomers is polymerized, however, a copolymer often results. The following structure represents a segment of a copolymer. Draw the structures of the two monomers that were copolymerized to form the copolymer.

Apeak with a retention time of 407 s has a width at half-height (w1/2) of 7.6 s. a neighboring peak is eluted 17 s later with a w1/2 of 9.4 s. a compound that is known not to be retained was eluted in 2.5 s. the peaks are not baseline resolved. how many theoretical plates would be needed to achieve a resolution of 1.5?

Hot air balloons float in the air because of the difference in density between cold and hot air. in this problem, you will estimate the minimum temperature the gas inside the balloon needs to be, for it to take off. to do this, use the following variables and make these assumptions: the combined weight of the pilot basket together with that of the balloon fabric and other equipment is w. the volume of the hot air inside the balloon when it is inflated is v. the absolute temperature of the hot air at the bottom of the balloon is th (where th> tc). the absolute temperature of the cold air outside the balloon is tc and its density is ďc. the balloon is open at the bottom, so that the pressure inside and outside the balloon is the same. as always, treat air as an ideal gas. use g for the magnitude of the acceleration due to gravity.

Problem #3 (ch. 1, problem 15)the ideal gas law provides one way to estimate the pressure exerted by a gas on a container. the law isí‘ťí‘ť=푛푛푛푛푛푛푉푉more accurate estimates can be made with the van der waals equationí‘ťí‘ť=푛푛푛푛푛푛푉푉â’푛푛푟푟â’푞푞푛푛2푉푉2where the term nb is a correction for the volume of the molecules and the term an2/v2is a correction for molecular attractions. the values of a and b depend on the type of gas. the gas constant is r, the absolutetemperature is t, the gas volume is v, and the number of moles of gas molecules is indicated by n. if n = 1 mol of an ideal gas were confined to a volume of v = 22.41 l at a temperature of 0â°c (273.2k), it would exert a pressure of 1 atm. in these units, r = 0.0826.for chlorine gas (cl2), a = 6.49 and b = 0.0562. compare the pressure estimates given by the ideal gas law and the van der waals equation for 1 mol of cl2 in 22.41 l at 273.2 k. what is the main cause of the difference in the two pressure estimates, the molecular volume or the molecular attractions?