The identity of a carbonyl-containing compound has been narrowed down to three possibilities: acetamide (ethanamide), acetone (propanone), or 1,1,1-trichloropropanone. 1H NMR and IR spectral data for the compound are given below. Determine the structure, and thus the identity, of the compound that gives the observed data.

a. acetone

b. tricolorpropnone

c. acetamide

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answer is: empirical formula is tl₂o. if we use 100 grams of compound, tha:

m(tl) = 96.2%  · 100 g ÷ 100%.

m(tl) = 96.2 g.

n(tl) = m(tl)  ÷ m(tl). n(tl) = 96.2 g  ÷ 204.4 g/mol.

n(tl) = 0.47 mol. m(o) = 3.77 g. n(o) = m(o)  ÷ m(o). n(o) = 3.77 g  ÷ 16 g/mol. n(ag) = 0.235 mol. n(tl) . n(o) = 0.47 mol : 0.235 mol /0.235. n(tl) . n(o) = 2 : 1.

m(tl₂o) = 204.4 g/mol  · 2 + 16 g/mol = 424.8 g/mol.

m(compound) = 456. 8 g/mol - 424.8 g/mol = 32 g/mol ( 2 oxygens); tl₂o₃.