Calculate the standard entropy of reaction at 298 K for the reaction Hg(liq) + Cl2(g) → HgCl2(s) The standard molar entropies of the species at that temperature are: Sºm (Hg, liq) = 76.02 J / (K mol) ; Sºm (Cl2,g) = 223.07 J / (K mol) ; Sºm (HgCl2,s) = 146.0 J / (K mol)

−153.1 J / (K mol)

Explanation:

Calculate the standard entropy of reaction at 298 K for the reaction Hg(liq) + Cl2(g) → HgCl2(s) The standard molar entropies of the species at that temperature are: Sºm (Hg,liq) = 76.02 J / (K mol) ; Sºm (Cl2,g) = 223.07 J / (K mol) ; Sºm (HgCl2,s) = 146.0 J / (K mol)

Hg(liq) + Cl2(g) → HgCl2(s)

Given that;

The standard molar entropies of the species at that temperature are:

Sºm (Hg,liq) = 76.02 J / (K mol) ;

Sºm (Cl2,g) = 223.07 J / (K mol) ;

Sºm (HgCl2,s) = 146.0 J / (K mol)

The standard molar entropies of reaction = Sºm[products] - Sºm [ reactants]

= 146.0 J / (K mol) – [76.02 J / (K mol) +223.07 J / (K mol) ]

= -153.09 J / (K mol)

= or -153.1 J / (K mol)

Hence the answer is  −153.1 J / (K mol)

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :