Chemistry, 28.06.2020 04:01 Rixi1227

The same reaction, with exactly the same amount of reactant, is conducted in a bomb calorimeter and in a coffee-cup calorimeter. In one measurement, qrxn=−13.3qrxn=−13.3 kJkJ in the other qrxn=−11.9qrxn=−11.9 kJkJ. Which value was obtained in the bomb calorimeter? (Assume that the reaction has a positive ΔVΔV in the coffee-cup calorimeter.)

Answers: 2

Show answers

Answers

Answer from: ellisc7044

$q_{rxn}$ = -13.3 KJ belongs to the bomb calorimeter

Explanation:

In this question, we are concerned with determining which of the two heats of reaction given, belongs to that in the bomb calorimeter

The kind of calorimetry used in a bomb calorimeter and a coffee-cup calorimeter is different.

In a bomb calorimeter, what we have is a constant volume calorimetry while in a coffee-cup calorimeter, what we have is a constant-pressure calorimetry.

For constant volume calorimetry, the change in volume ΔV = 0 while for constant pressure calorimetry, the change in pressure ΔP = 0.

Mathematically, the relationship between the change in internal energy Δ $E_{rxn}$ of the reaction, the work of the reaction $w_{rxn}$ and the heat of the reaction $q_{rxn}$ is given by;

Δ $E_{rxn}$ = $w_{rxn}$ + $q_{rxn}$

Kindly note that, in a bomb calorimeter, the work of the reaction $w_{rxn}$ = 0

Thus, this means that for a bomb calorimeter,

Δ $E_{rxn}$ = $q_{rxn}$

This means that in the bomb calorimeter, the entire internal energy change is converted to heat of the reaction.

In the case of the coffee-cup calorimeter, the work of the reaction is non-zero and it is equal to the product of the pressure and the change in volume.

Thus, mathematically,

$w_{rxn}$ = PΔV

Thus;

Δ $E_{rxn}$ = $w_{rxn}$ + $q_{rxn}$ = PΔV + $q_{rxn}$

Since for a coffee cup calorimeter, the change in volume is positive(as given in the question), this means that;

ΔV > 0

and PΔV > 0

This automatically means that

Δ $E_{rxn}$ > $q_{rxn}$

Hence, in the coffee cup calorimeter, the entire change in internal energy is not converted to heat as part is used to do useful work.

Thus, this means that in the coffee cup calorimeter, the value of change in internal energy is greater than the value of heat.

This makes the magnitude of heat in the bomb calorimeter greater than that of the coffee cup calorimeter.

Since -13.3 KJ is the bigger magnitude of the two, then it belongs to the bomb calorimeter

Answer from: Quest

Sorry i dont understand the question can you rephase it?

Answer from: Quest

Ithe undersigned only for use your own email and delete any and copies and of the itself and to be there is a good timewhat does a decrease in temperature indicate about the molecules in a sample of liquid water? decreased chemical energy of the moleculesdecreased kinetic energy of the moleculesincreased chemical energy of the moleculesincreased kinetic energy of the moleculeshow does a sample of helium at 15 â°c compare to a sample of helium at 215 k? the helium at 15 â°c has a higher average kinetic energy than the sample at 215 k.the helium at 15 â°c has lower nuclear energy than the sample at 215 k.the helium at 15 â°c has slower-moving atoms than the sample at 215 k.the helium at 15 â°c has smaller atoms than the sample at 215 k.