Predict which of the following pairs of solutions, when mixed together, will cause a precipitate to form. (Select all that apply.) Ksp values are: CoS 4.0 × 10–21 Hg2Cl2 3.5 × 10–18 PbCl2 2.4 × 10–4 Ag2SO4 1.5 × 10–5 Group of answer choices 1.5 L of 0.025 M BaCl2 and 1.25 L of 0.014 M Pb(NO3)2 25 mL of 1 × 10–5 M Co(NO3)2 and 75 mL of 5 × 10–4 M Na2S 500 mL of 7.5 × 10–4 M AlCl3 and 100 mL of 1.7 × 10–5 M Hg2(NO3)2. 650 mL of 0.0080 M K2SO4 and 175 mL of 0.15 M AgNO3

25 mL of 1 × 10–5 M Co(NO₃)₂ and 75 mL of 5 × 10–4 M Na₂S

500 mL of 7.5 × 10–4 M AlCl₃ and 100 mL of 1.7 × 10–5 M Hg₂(NO₃)₂.

650 mL of 0.0080 M K₂SO₄ and 175 mL of 0.15 M AgNO₃

Explanation:

When 2 compounds that produce an insoluble substance are mixed together, A precipitate will be formed if Q of reaction > Ksp

For the solutions:

1.5 L of 0.025 M BaCl₂ and 1.25L of 0.014 M Pb(NO₃)₂.

Ksp is:

PbCl₂(s) ⇄ Pb²⁺(aq) + 2Cl⁻(aq)

Ksp = 2.4x10⁻⁴ = [Pb²⁺][Cl⁻]²

Molar concentration of each ion is:

[Pb²⁺] =  1.25L ₓ (0.014mol / L) = 0.0175mol / 2.75L = 6.36x10⁻³M

[Cl⁻] = 2 ₓ 1.5L ₓ (0.025mol / L) = 0.075mol / 2.75L = 0.0273M

Replacing in Ksp expression to find Q:

Q = [6.36x10⁻³M][0.0273M]² = 4.73x10⁻⁶

As Q < Ksp, the mixture will not produce a precipitate.

25 mL of 1 × 10–5 M Co(NO₃)₂ and 75 mL of 5 × 10–4 M Na₂S

Ksp is:

CoS(s) ⇄ Co²⁺(aq) + S²⁻(aq)

Ksp = 4.0x10⁻²¹ = [Co²⁺][S²⁻]

Molar concentration of each ion is:

[Co²⁺] =  0.025L ₓ (1x10⁻⁵mol / L) = 2.5x10⁻⁷mol / 0.1L = 2.5x10⁻⁶M

[S²⁻] = 0.075L ₓ (5x10⁻⁴mol / L) = 3.75x10⁻⁵mol / 0.1L = 3.75x10⁻⁴M

Replacing in Ksp expression to find Q:

Q = [2.5x10⁻⁶M][3.75x10⁻⁴M] = 9.38x10⁻⁶

As Q > Ksp, the mixture will produce a precipitate.

500 mL of 7.5 × 10–4 M AlCl₃ and 100 mL of 1.7 × 10–5 M Hg₂(NO₃)₂.

Ksp is:

Hg₂Cl₂(s) ⇄ 2Hg⁺(aq) + 2Cl⁻(aq)

Ksp = 3.5x10⁻¹⁸ = [Hg⁺]²[Cl⁻]²

Molar concentration of each ion is:

[Hg⁺] =  2ₓ0.100L ₓ (1.7x10⁻⁵mol / L) = 3.4x10⁻⁶mol / 0.6L = 5.67x10⁻⁶M

[Cl⁻] = 3 ₓ 0.500L ₓ (7.5x10⁻⁴mol / L) = 1.125x10⁻³mol / 0.6L = 1.88x10⁻³M

Replacing in Ksp expression to find Q:

Q = [5.67x10⁻⁶M]²[1.88x10⁻³M]² = 1.14x10⁻⁶

As Q > Ksp, the reaction will produce a precipitate.

650 mL of 0.0080 M K₂SO₄ and 175 mL of 0.15 M AgNO₃

Ksp is:

Ag₂SO₄(s) ⇄ 2Ag⁺(aq) + SO₄²⁻(aq)

Ksp = 1.5x10⁻⁵ = [Ag⁺]²[SO₄²⁻]

Molar concentration of each ion is:

[Ag⁺] =  0.175L ₓ (0.15mol / L) = 0.02625mol / 0.825L = 0.0318M

[SO₄²⁻] = 0.650L ₓ (0.080mol / L) = 0.052mol / 0.825L = 0.0630M

Replacing in Ksp expression to find Q:

Q = [0.0318M]²[0.0630M] = 6.37x10⁻⁵

As Q > Ksp, the reaction will produce a precipitate.

1.consider the following balanced equation and answer parts a through. show calculations for each part.  

3 ag(s) + 4 hno3(aq) → 3 agno3(aq) + no(g) + 2 h2o(l)  

a. calculate the number of moles of agno3 produced by the reaction of 3 moles of ag with excess hno3. if the number to the left of the compound represents the number of moles of the compound which are present, then 3 moles of ag react with 4 moles hno3 to produce 3 moles agno3 (aq).

so the answer to a would be 3 moles.

b. calculate the number of moles of agno3 produced by the reaction of 108 grams of ag with excess hno3.  

i'm not sure how to plug in the grams of silver into an equation using moles to find how many moles are produced.

c. calculate the number of grams of agno3 produced by the reaction of 108 grams of ag with excess hno3  

d. calculate the number of moles of no produced as a byproduct of the reaction of 108 grams of ag with excess hno3.  

e. calculate the number of grams of no produced as a byproduct starting with 108 grams of ag and excess hno3.  

explanation:

what is the average time it took the car to travel 0.25 meters?

⇒ 2.23 seconds

what is the average time it took the car to travel 0.50 meters?

⇒ 3.13 seconds