50.0 mL each of 1.0 M HCl and 1.0 M NaOH, at room temperature (20.0 OC) are mixed. The temperature of the resulting NaCl solution increases to 27.5 OC. The density of the resulting NaCl solution is 1.02 g/mL. The specific heat of the resulting NaCl solution is 4.06 J/g OC Calculate the Heat of Neutralization of HCl(aq) and NaOH(aq) in KJ/mol NaCl produced

-62.12kJ/mol is heat of neutralization

Explanation:

The neutralization reaction of HCl and NaOH is:

HCl + NaOH → NaCl + H₂O + HEAT

An acid that reacts with a base producing a salt and water

You can find the released heat of the reaction  -heat of neutralization- (Released heat per mole of reaction) using the formula:

Q = C×m×ΔT

Where Q is heat, C specific heat of the solution (4.06J/gºC), m its mass of the solution and ΔT change in temperature (27.5ºC-20.0ºC = 7.5ºC).

The mass of the solution can be found with the volume of the solution (50.0mL of HCl solution + 50.0mL of NaOH solution = 100.0mL) and its density (1.02g/mL), as follows:

100.0mL × (1.02g / mL) = 102g of solution.

Replacing, heat produced in the reaction was:

Q = C×m×ΔT

Q = 4.06J/gºC×102g×7.5ºC

Q = 3106J = 3.106kJ of heat are released.

There are 50.0mL ×1M = 50.0mmoles = 0.0500 moles of HCl and NaOH that reacts releasing 3.106kJ of heat. That means heat of neutralization is:

3.106kJ / 0.0500mol of reaction =

The - is because heat is released, absorbed heat has a + sign

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