A 45.0 mL sample of 0.020 M acetic acid (HC2H3O2) is titrated with 0.020 M NaOH.? Determine the pH of the solution after adding 35.0 mL of any NaOH. (Ka of acetic acid is 1.8 x 10-5) HC2H3O2 (aq) + NaOH (aq) D NaC2H3O2(aq) + H2O (l) (Hint: Calculate new concentration and ICE table)

Explanation:

CH₃COOH + NaOH = CH₃COONa + H₂O .

.02M

CH₃COOH  = CH₃COO⁻ + H⁺

C                       xC             xC

Ka = xC . xC / C = x² C

1.8 x 10⁻⁵ = x² . .02

x² = 9 x 10⁻⁴

x = 3 x 10⁻²

= .03

concentration of H⁺ = xC = .03 . .02

= 6 x 10⁻⁴ M , volume =  45 x 10⁻³ L

moles of H⁺  = 6 X 10⁻⁴  x 45 x 10⁻³

= 270 x 10⁻⁷ moles

= 2.7 x 10⁻⁵ moles

concentration of NaOH = .0200 M , volume = 35 x 10⁻³ L

moles of Na OH = 2 X 10⁻²  x 35 x 10⁻³

= 70 x 10⁻⁵ moles

=  

NaOH is a strong base so it will dissociate fully .

there will be neutralisation reaction between the two .

Net NaOH remaining = (70 - 2.7 ) x 10⁻⁵ moles

= 67.3 x 10⁻⁵ moles of NaOH

Total volume = 45 + 35 = 80 x 10⁻³

concentration of NaOH after neutralisation.= 67.3  x 10⁻⁵ / 80 x 10⁻³ moles / L

= 8.4125  x 10⁻³ moles / L

OH⁻ = 8.4125  x 10⁻³

H⁺ = 10⁻¹⁴ / 8.4125  x 10⁻³

= 1.1887 x 10⁻¹²

pH = - log (  1.1887 x 10⁻¹² )

= 12 - log 1.1887

= 12 - .075

= 11.925 .

mechanics (greek   is that area of science concerned with the behaviour of physical bodies when subjected to forces or displacements, and the subsequent effects of the bodies on their environment. the scientific discipline has its origins in ancient greece with the writings of aristotle and archimedes[1][2][3] (see history of classical mechanics and timeline of classical mechanics). during the early modern period, scientists such as galileo, kepler, and newton laid the foundation for what is now known as classical mechanics. it is a branch of classical physics that deals with particles that are either at rest or are moving with velocities significantly less than the speed of light. it can also be defined as a branch of science which deals with the motion of and forces on objects. the field is yet less widely understood in terms of quantum theory.

explanation: