Which of the following should have the highest conductivity? a. 3.0 M NaCl b. 2.1 M Na3PO4 c. 2.4 M CaCl2 d. 3.2 M NH4NO3

The correct answer is option b, that is, 2.1 M Na₃PO₄.

Explanation:

The solution with the largest concentration of ions will possess the highest conductivity.

a) 3.0 M NaCl

NaCl ⇔ Na⁺ + Cl⁻

Here the total number of ions is 2, therefore, the concentration of ions is 3.0 × 2 = 6.0 M

b) 2.1 M Na₃PO₄

Na₃PO₄ ⇔ 3 Na⁺ + PO₄³⁻

Here the total number of ions i 4. Therefore, the concentration of ions is

2.1 × 4 = 8.4 M.

c) 2.4 M CaCl₂

CaCl₂ ⇔ Ca²⁺ + 2Cl⁻

The total number of ions is 3. Therefore, the concentration of ions is

2.4 × 3 = 7.2 M

d) 3.2 M NH₄NO₃

NH₄NO₃ ⇔ NH₄⁺ + NO₃⁻

The total number of ions is 2. The concentration of ions will be,

3.2 × 2 = 6.4 M

Hence, the highest conductivity will be of 2.1 M Na₃PO₄.

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