I'm having trouble solving this maze. I would appreciate any help. Thanks.

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

Which is the solubility product expression for caf2(s)?  [ca2+]/[f–]2  [ca2+][f2–]  [ca]+[f]2  [ca2+][f–]2

Why do lunar and solar eclipse not happen every month