At a certain temperature this reaction follows first-order Kinetics with a rate constant of 0.0660 2H1 (g)> H2, (g)+I2
Suppose a vessel contains HI at a concentration of 0.310 M. Calculate how long it takes for the concentration of HI to decrease to 0.0558 M. You may assume no other reaction is important. Round your answer to 2 significant digits.

After 26.0s, the concentration of HI decreases from 0.310M to 0.0558M.

Explanation:

Based on the reaction of the problem, you have as general kinetic law for a first-order reaction:

ln[HI] = -kt + ln [HI]₀

Where [HI] is actual concentration after time t,

k is rate constant

and [HI]₀ is initial concentration of the reactant.

Initial concentration of HI is 0.310M,

K is 0.0660s⁻¹,

And the actual concentration is 0.0558M:

ln[HI] = -kt + ln [HI]₀

ln[0.0558M] = -0.0660s⁻¹*t + ln [ 0.310M]

-1.7148 = -0.0660s⁻¹*t

26.0s = t

the answer is:  

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