Which of the following is likely to be the most valid source of information about pollution?

Can someone me with these questions plz.

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

Agroup of students is studying convection current. they fill two identical balloons with the same amount of helium. one balloon is placed in a freezer and the other is in an area with warm air. after 10 minutes, the balloon are released from a height of 1 meter. which of the following to the students most likely observe? a) the warm balloon expands and rises. the cold balloon shrinks and sinks b) the balloon both rise. the cold balloon is larger than the warm balloon c) the cold balloon expands and rises. the warm balloon shrinks and sinks d) the balloon rise at the same rate. both balloons are the same size