A solution containing a mixture of 0.0333 M0.0333 M potassium chromate ( K2CrO4K2CrO4 ) and 0.0532 M0.0532 M sodium oxalate ( Na2C2O4Na2C2O4 ) was titrated with a solution of barium chloride ( BaCl2BaCl2 ) for the purpose of separating CrO2−4CrO42− and C2O2−4C2O42− by precipitation with the Ba2+Ba2+ cation. The solubility product constants ( KspKsp ) for BaCrO4BaCrO4 and BaC2O4BaC2O4 are 2.10×10−102.10×10−10 and 1.30×10−61.30×10−6 , respectively. A) Which barium salt will precipitate first? O BaC204 O BaCrO4
B) What concentration of Ba2+ must be present for BaCrO4 to begin precipitating? Number [Ba2+]=
C) What concentration of Ba is required to reduce oxalate to 10% of its original concentration? Number 2+
D) What is the ratio of oxalate to chromate (IC204CrO4) when the Ba2 concentration is 0.0050 M? Number C, O Cro,