The property of a substance stays no matter how the substance is used.

Any substance changes to another substance that means the change of the physical property. Like water () has different state which changes as the temperature changes. It remain as liquid in the room temperature, in solid form at or below 0°C and vapor phase on or above 100°C. But in all the stage or phase of the substance the composition of the water i.e.  remains. Thus the chemical property remains fixed when a substance change to other substance.  

a rain shadow is a dry region of land on the side that is protected against the prevailing winds of a mountain range. the prevailing winds are the winds that occur most of the time in a particular place of the earth

prevailing winds carry air toward the mountain range. as the air rises up over a mountain range, the air cools, water vapor condenses, and clouds form. on this side of the mountains, called the windward side, precipitation falls in the form of  rain  or snow. this dry air produces a  rain shadow.

im pretty sure its b