You have a carbonate buffer with pH 10.3 and a concentration of 2.0 M. What is the buffer capacity of 100 mL of the buffer against 3.0 M CsOH?

Explanation:

pH = 10.3

[ H] = 10⁻¹⁰°³

= 5 x 10⁻¹¹ M

concentration of CsOH C = 3 M

pKa of carbonate = 6.35

Ka = 10⁻⁶°³⁵ = 4.46 x 10⁻⁷

Buffer capacity = 2.303 x C x Ka x [ H⁺] / ( Ka + [ H⁺]² )²

= 2.303 x 3 x 4.46 x 10⁻⁷  x 5 x 10⁻¹¹ / ( 4.46 x 10⁻⁷  + 25 x 10⁻²² )²

= 154 x 10⁻¹⁸ / 19.9 x 10⁻¹⁴

= 7.74 x 10⁻⁴ .

the product of the pressure and volume is also constant