Please help it's a emergency

Initially, the balloon had 3.0 liters of gas at a pressure of 400 kpa and was at a temperature of 294 k. if the balloon is cooled to 277 k and its volume decreased to 1 l, what will the new pressure in the balloon be?

Why do you suppose the structural polysaccharide cellulose does not contain branches? why do you suppose the structural polysaccharide cellulose does not contain branches? branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into globules, thereby decreasing the flexibility and strength of the globules. branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into microfibrils, thereby increasing the rigidity and strength of the microfibrils. branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into globules, thereby increasing the flexibility and strength of the globules. branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into microfibrils, thereby decreasing the rigidity and strength of the microfibrils.

Mary is conducting an experiment on how pollution affects plant growth. how can she ensure that her data are reliable?