Can someone tell me which two are wrong?

Amixture with the same composition throughout is!

Consider hydrogen in an excited state n = 5n=5 that emits photons to reach the ground state. there are various possible transitions other than straight to the ground state that can occur; for example, it can drop to the n = 3n=3 state followed by the n = 3n=3 to the ground state transition. which of the possible transitions will result in the emission of a photon in the visible region?

In vapor-liquid equilibrium in a binary mixture, both components are generally present in both phases. how many degrees of freedom are there for such a system? the reaction between nitrogen and hydrogen to form ammonia occurs in the gas phase. how many degrees of freedom are there for this system? steam and coal react at high temperatures to form hydrogen, carbon monoxide, carbon dioxide, and methane. the following reactions have been suggested as being involved in the chemical transformation: