Question is in image format given below. Need to know order of reaction, Activation energy and Frequency factor as soon as possible :)

Initially, the balloon had 3.0 liters of gas at a pressure of 400 kpa and was at a temperature of 294 k. if the balloon is cooled to 277 k and its volume decreased to 1 l, what will the new pressure in the balloon be?

What is an example of a physical property?

Indicate whether the specified alkyl halides will form primarily substitution products, only elimination products, both substitution and elimination products, or no products when they react with sodium methoxide. 1-bromobutane 1-bromo-2-methylpropane 2-bromobutane 2-bromo-2-methylpropane