A different brand of iron tablet was analysed by Hitration with 0.0093 mol. L" potassium dichromate via the reaction listed below;
Cr2O72- + 6Fe2+ + 14H+ + 2Cr3+ + 6Fe3+ + 7H20
In this experiment 4 tablets were crushed and dissolved in 200 cm3 of dilute acid. 25cm3
of this solution was used in the titration. The results of the titrations were as follows;
Titration Volume dichromate (cm)
1
33.0
2
32.05
3
32.15
4
32.10
Calculate the concentration of iron used in the titration (4 dp).
C1V1/C2V2 = n/n2

The concentration of iron used in the titration : 0.009 M

Given

Reaction

Cr₂O₇²⁻ + 6Fe²⁺ + 14H⁺ ⇒ 2Cr³⁺ + 6Fe³⁺ + 7H₂O

0.0093 mol/L potassium  dichromate

200 cm³ of dilute acid, 25cm³   was used in the titration.

Required

the concentration of iron

Solution

Titration formula

C₁V₁n₁=C₂V₂n₂⇒ From equation : n₁=6n₂(1=Cr₂O₇, 2=Fe)

titration average : 33+32.05+32.15+32.1 / 4 = 32.325 cm³(ml)

25 cm³ of iron solution used in titration :

Dilution(25 ml from 200 ml iron solution)

answer: c. the experiment shows that the red substance experienced a chemical change.

explanation: chemical change is the change in which chemical composition of the substance changes. physical change is the change in which there is no change in chemical composition.

chemical changes are accompanied by following changes:

a) precipitate formation

b) energy is released or absorbed

c) formation of bubbles

d) change in color

as it is given that the red color has disappeared and there is production of gas, it means the red substance has undergone a chemical change.

e

confused

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