Who can help ? For BRAINLIST ( 6th grade work btw ) please help me

1. suppose a reaction mixture, when diluted with water, afforded 300 ml of an aqueous solution of 30 g of the reaction product malononitrile [ch2(cn)2], which is to be isolated by extraction with ether. the solubility of malononitrile in ether at room temperature is 20.0 g/100 ml, and in water is 13.3 g/100 ml. what weight of malononitrile would be recovered by extraction with (a) three 100-ml portions of ether and (b) one 300-ml portion of ether? suggestion: for each extraction, let x equal the weight extracted into the ether layer. in part (a), the concentration in the ether layer is x/100 and in the water layer is (30 x)/300; the ratio of these quantities is equal to k 20/13.3.

When 225mg of anthracene, c14h10(s), was burned in a bomb calorimeter the temperature rose by 1.75k. calculate the calorimeter constant. by how much will the temperature rise when 125mg of phenol, c6h5oh(s), is burned in the calorimeter under the same conditions? (δch< (c14h10,s)=–7061 kj mol−1.)

How will the volume of a gas be affected if the pressure is tripled, but the temperature remains the same?