How many moles of nitrogen gas are used up in a reaction that produces 2.4X10^1 moles of ammonia?

Which aqueous solution of ki freezes at the lowest temperature? 1) 1 mol of ki in 500. g of water 2) 2 mol of ki in 500. g of water 3) 1 mol of ki in 1000. g of water 4) 2 mol of ki in 1000. g of water