Help me out please with these amazing questions

Kc = 0.040 for the system below at 450oc. if a reaction is initiated with 0.40 mole of cl2 and 0.40 mole of pcl3 in a 2.0 liter container, what is the equilibrium concentration of cl2 in the same system? pcl5(g) ⇄ pcl3(g) + cl2(g)

The excretory system,need answers for all: )

Hydrogenation reactions, in which h2 and an "unsaturated" organic compound combine, are used in the food, fuel, and polymer industries. in the simplest case, ethene (c2h4) and h2 form ethane (c2h6). if 140 kj is given off per mole of c2h4 reacting, how much heat (in mj) is released when 12 kg of c2h6 forms?