The Mohrig textbook (pp. 366-376, 4rd Edition) illustrates how chemical shift values can be estimated using given database tables and base values. Use Tables 22.3 and 22.4 and the worked examples to estimate the chemical shift value for Ha and Hc. Show your work for full credit. How closely do the calculated values agree with the actual values

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it can be observed without changing the identity of the object.

it depends on what substance you're talking about as well as many other factors. in quantum mechanics, the observation of particles affects the observers ability to measure certain properties. for example: you can know the velocity of a particle, but you can't know it's position; or you can know it's position, but not it's velocity. it's like trying to find out where a grain of sand is by throwing other grains of sand at it. once you find out where it is, it's been moved. it's also like trying to find an answer to the question of whether or not a tree falling in a forest makes a sound if nobody is there to hear it. paradoxically, the only way to find out is to be there and hear it.