This compound is treated with two different oxidizing reagents: either H2CrO4 and H2SO4, or with PCC. Draw the major organic product for each of the oxidation reactions. Do not draw inorganic by-products.

Nanotechnology, the field of trying to build ultrasmall structures one atom at a time, has progressed in recent years. one potential application of nanotechnology is the construction of artificial cells. the simplest cells would probably mimic red blood cells, the body's oxygen transporters. for example, nanocontainers, perhaps constructed of carbon, could be pumped full of oxygen and injected into a person's bloodstream. if the person needed additional oxygen-due to a heart attack perhaps, or for the purpose of space travel-these containers could slowly release oxygen into the blood, allowing tissues that would otherwise die to remain alive. suppose that the nanocontainers were cubic and had an edge length of 24 nanometers. part a part complete what is the volume of one nanocontainer? (ignore the thickness of the nanocontainer's wall.) express your answer using two significant figures. v v = 1.4ă—10â’20 l previous answers correct significant figures feedback: your answer 1.3824â‹…10â’20 = 1.382ă—10â’20 l was either rounded differently or used a different number of significant figures than required for this part. if you need this result for any later calculation in this item, keep all the digits and round as the final step before submitting your answer. part b suppose that each nanocontainer could contain pure oxygen pressurized to a density of 81 g/l . how many grams of oxygen could be contained by each nanocontainer?

Two nitro no2 groups are chemically bonded to a patch of surface. they can't move to another location on the surface, but they can rotate (see sketch at right). it turns out that the amount of rotational kinetic energy each no2 group can have is required to be a multiple of ε, where =ε×1.010−24 j. in other words, each no2 group could have ε of rotational kinetic energy, or 2ε, or 3ε, and so forth — but it cannot have just any old amount of rotational kinetic energy. suppose the total rotational kinetic energy in this system is initially known to be 32ε. then, some heat is removed from the system, and the total rotational kinetic energy falls to 18ε. calculate the change in entropy. round your answer to 3 significant digits, and be sure it has the correct unit symbol.

When a spring is compressed, the energy changes from kinetic to potential. which best describes what is causing this change?