Please help and thank you

1. calculate the approximate enthalpy of the reaction in joules. estimate that 1.0 ml of vinegar has the same thermal mass as 1.0 ml of water. iqnore the thermal mass of th sodium bicarbonate. note: it takes about 4.2 joules () to change 1.0 gram (1.0ml) of water 1.0 c

How many moles are in 250 grams of tungsten (w)? * 4.4x10^23 moles 4.2x10^23 moles 0.7 moles 1.4 moles

Calculate the expected ph values of the buffer systems from the experiments (a,b,c,d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.