Can someone help please

Based on the law of conservation of energy, which statement is false? answer- energy is lost when machines dont work right

Initially, the balloon had 3.0 liters of gas at a pressure of 400 kpa and was at a temperature of 294 k. if the balloon is cooled to 277 k and its volume decreased to 1 l, what will the new pressure in the balloon be?

13. calculate the initial concentration (before precipitation) of carbonate ions after the addition of each 0.05 ml of solution b to the 1.00 l beaker of solution a. divide the work among group members and write the answers in the table in model 3. assume the volume change as solution b is added is negligible. 14. notice the initial concentrations of zn2+ - and cu2+ in the table in model 3. a. explain how these were obtained from the data in model 2. b. as solution b is added and precipitates form, do these initial concentrations change? 15. use the data in model 2 to indicate the presence of precipitate (either znco3 or cuco3) after each 0.05 ml addition of solution b in model 3. 16. use the initial concentrations of carbonate ions and zinc ions to calculate the reaction quotient, qsp for the zinc carbonate scenarios in model 3. divide the work among group members and write the answers in the table in model 3. 17. use the initial concentrations of carbonate ion and copper(ii) ions to calculate the qsp for the copper(ii) carbonate scenarios in model 3. divide the work among group members and write the answers in the table in model 3.