Potassium chlorate, a common oxidizing agent in fireworks and matchheads, undergoes a solid-state disproportionation reaction when heated:
4KClO3 (s) ⟶ Δ3KClO4 (s) + KCl (s).
Use ΔHf ° and S° values to calculate ΔG_sys ° (which is ΔGrxn °) in kJ at 25°C for this reaction.
Answers: 3
![\implies G^0_{rxn} = 3 \times \Delta _fG^0 [KClO_4{(s)}] + \Delta_fG^0[KCl_{(s)}] - 4 \times \Delta _f G^0 [ KClO_3 (s) ]](/tpl/images/1206/8925/2b60b.png)
![\Delta _fG^0 \ values \ at \ 25^0 \ C (298 \ K) are\ given \ as:\\\\ \Delta _fG^0 [KClO_4(s)] = -303.09 \ kJ \\ \\ \Delta _fG^0 [KCl(s) ] = - 409.14 \ kJ \\ \\ \Delta_f G^0 [KClO_3_{(s)}] = -296.25 \ kJ \\ \\ replacing \ the \ above \ values \ into \ equation (1) ; then:\\ \\ \\\Delta G^0_{rxn} = 3 *(-303.09) + (-409.14) - 4*(-296.25) \ kJ \\ \\ = (-909.27 - 409.14 + 1185) \ kJ \\ \\ = -133.41 \ kJ \\ \\ \mathbf{\Delta G^0_{rxn} = -133.4 \ kJ }](/tpl/images/1206/8925/f4981.png)
Another question on Chemistry
Chemistry, 23.06.2019 00:30
How can you write e method for the experiment of separating sand from water by filtration process? 1-materials 2-steps 3-conclusion also the same for the separating process of water and salt by filtration or distillation. quick because i need to finish my hw
Answers: 2
Chemistry, 23.06.2019 09:00
Need ! assume that the variables x and y are directly related. if k = 8, what is the value for each of the following points? be sure and record your data to be used in the following problem. x y k 0.
Answers: 2
You know the right answer?
Potassium chlorate, a common oxidizing agent in fireworks and matchheads, undergoes a solid-state di...
Questions
English, 31.07.2019 23:30
Mathematics, 31.07.2019 23:30
Mathematics, 31.07.2019 23:30
History, 31.07.2019 23:30
English, 31.07.2019 23:30
Mathematics, 31.07.2019 23:30
Mathematics, 31.07.2019 23:30
Chemistry, 31.07.2019 23:30
Mathematics, 31.07.2019 23:30
Mathematics, 31.07.2019 23:30
