Choose the options below that are true. A. The rate law for a given reaction can be determined from a knowledge of the rate-determining step in that reaction's mechanism.
B. The rate laws of all chemical reactions can be determined directly from their net chemical equations.
C. The rate laws of bimolecular elementary reactions are second order overall.
D. The rate law for a given reaction can be determined from its reaction mechanism, without the accompanying rates of each elementary step in the mechanism.

The options (A) -The rate law for a given reaction can be determined from a knowledge of the rate-determining step in that reaction's mechanism.  and (C) -The rate laws of bimolecular elementary reactions are second order overall ,is true.

Explanation:

(A) -The rate law can only be calculated from the reaction's slowest or rate-determining phase, according to the first sentence.

(B) -The second statement is not entirely right, since we cannot evaluate an accurate rate law by simply looking at the net equation. It must be decided by experimentation.

(C) -Since there are two reactants, the third statement is correct: most bimolecular reactions are second order overall.

(D)-The fourth argument is incorrect. We must track the rates of and elementary phase that is following the reaction in order to determine the rate.

Therefore , the first and third statement is true.