I need Help with chem test #3

Which statement describes james chadwick’s discovery.

The rate constant for the reaction below is 6.2 x 10−5 mol l−1 s −1. if the initial concentration of a is 0.0500 m, what is its concentration after 115 s?

Imagine if during the cathode ray experiment, the size of the particles of the ray was the same as the size of the atom forming the cathode. which other model or scientific observation would have also been supported? 1. this would support dalton's postulates that proposed the atoms are indivisible because no small particles are involved. 2. this would support bohr's prediction about electrons moving in orbits having specific energy. 3. this would support bohr's prediction about electrons being randomly scattered around the nucleus in the atom. 4. this would support dalton's postulates that proposed that atoms combine in fixed whole number ratios to form compounds.