Assuming that no equilibria other than dissolution are involved, calculate the concentration of all solute species in each of the following solutions of salts in contact with a solution containing a common ion. Show that changes in the initial concentrations of the common ions can be neglected. (a) AgCl(s) in 0.025 M NaCl (b) CaF2(s) in 0.00133 M KF (c) Ag2SO4(s) in 0.500 L of a solution containing 19.50 g of K2SO4 (d) Zn(OH)2(s) in a solution buffered at a pH of 11.45

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. in the first step, calcium carbide and water react to form acetylene and calcium hydroxide: cac2 (s) + 2h2o (g) → c2h2 (g) + caoh2 (s) =δh−414.kj in the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6c2h2 (g) + 3co2 (g) + 4h2o (g) → 5ch2chco2h (g) =δh132.kj calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. round your answer to the nearest kj .