How could a sample of gas be collected at the positive electrode? (electrolysis)

Consider the following system at equilibrium. caco3(s) ca2+(aq) + co32–(aq) the addition of which compound will cause a shift in equilibrium because of a common ion effect? ccl4 co2 cuso4 na2co3

If a solution is considered basic, then a) the hydroxide ion and hydronium ion concentrations are equal. b) the hydroxide ion concentration is less than the hydronium ion concentration. c) the hydronium ion concentration is greater than the hydroxide ion concentration. d) the hydroxide ion concentration is greater than the hydronium ion concentration.

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?