Can someone confirm that this is right?

A100-watt light bulb radiates energy at a rate of 100 j/s. (the watt, a unit of power or energy over time, is defined as 1 j/s.) if all of the light emitted has a wavelength of 525 nm , how many photons are emitted per second?

Using a value of ksp = 1.8 x 10-2 for the reaction pbcl2 pb+2(aq) + 2cl -(aq). if the value of ksp was determined to be only 1.2 x 10-2: too much solid has dissolved. additional precipitate is forming. the solution is unsaturated. the ions are now combining to reduce their concentrations.

How many grams of co(g) are there in 74.5 ml of the gas at 0.933 atm and 30o c?