Diazomethane, CH2N2, is used in the organic chemistry laboratory despite its danger because it produces very high yields and is selective for reaction with carboxylic acids. Draw the product of the reaction of this compound with excess diazomethane in methanol. Include H atoms at chiral centers only. If a group is achiral, do not use wedged or hashed bonds on it. Do not include lone pairs in your answer.

Part b: study of equilibrium on solubility: mg(oh)2(s) ⇌ mg2+(aq) + 2 oh–(aq) cloudy clear (pink) 7. a. b. 8. a. b. 9. 10. 11. 12. when adding concentrated hydrochloric acid, how did the appearance of the equilibrium mixture change? the change in appearance indicated a shift in the point of equilibrium. in which direction did the equilibrium shift? (l) left (r) right explain your answer to question 7a. you should indicate which ion was added to or removed from the equilibrium mixture. when adding edta, how did the appearance of the equilibrium mixture change? the change in appearance indicated a shift in the point of equilibrium. in which direction did the equilibrium shift? (l) left (r) right explain your answer to question 8a. you should indicate which ion was added to or removed from the equilibrium mixture. upon heating in which direction is the equilibrium shifting? upon cooling in which direction is the equilibrium shifting? is the forward reaction a. endothermic explain your answers to questions 9, 10, and 11. (l) left (r) right (l) left (r) right b. exothermic

7. using your knowledge of colligative properties explain whether sodium chloride or calcium chloride would be a more effective substance to melt the ice on a slick sidewalk. use 3 – 4 sentences in your explanation. 8. when a 2.5 mol of sugar (c12h22o11) are added to a certain amount of water the boiling point is raised by 1 celsius degree. if 2.5 mol of aluminum nitrate is added to the same amount of water, by how much will the boiling point be changed? show all calculations leading to your answer or use 3 – 4 sentences to explain your answer. 9. if 5.40 kcal of heat is added to 1.00 kg of water at 100⁰c, how much steam at 100⁰c is produced? show all calculations leading to an answer. 10. the freezing of water at 0⁰c can be represented as follows: h2o (l) ↔ h2o(s) the density of liquid water is 1.00 g/cm3. the density of ice is 0.92 g/cm3. in 3 – 4 sentences explain why applying pressure causes ice to melt.

What is the mass of 0.46 mol of mgcl2